Olympiacos vs PSV Prediction for 5 November 2025 - Football

🔈 Can the Greek club secure their first victory in this European campaign? One of the standout fixtures of the Champions League's third round is the clash between Olympiacos and PSV. Both teams are in need of points to strengthen their standings and boost their chances of advancing to the playoffs. Despite Olympiacos having home advantage, bookmakers anticipate a level playing field, giving equal odds for success to both sides.

Head-to-Head

📊 These clubs last clashed in the Round of 32 of the 2020/21 UEFA Europa League. The Greek side advanced to the next stage thanks to a commanding 4-2 home victory. We'll soon find out if the "Red and Whites" can once again outplay the "Farmers."

Olympiacos Team Overview

🔴 The Greek club has had an unconvincing start in the current Champions League campaign. It all began with an unexpected draw at home against Pafos (0-0). Despite Olympiacos having a numerical advantage from the 26th minute, they failed to convert their dominance into a victory. The point gained against the Cypriots remains the only one for Jose Luis Mendilibar's squad in this season's premier European competition. In the national league, the "red-and-whites" continue to battle for the top spot in the standings, challenging PAOK.

⚪ In the last round of the Champions League, Olympiacos visited Catalan giants Barcelona (1-6). While the "red-and-whites" managed to hold off their formidable opponents for a period, their tactical plan unraveled after conceding the third goal. The Greeks were further undone by Santiago Hezze's red card in the 57th minute. Notably, Mendilibar's side has the least effective attacking line in the tournament, averaging just 0.33 goals per match. Last weekend, Olympiacos lifted their spirits and those of their fans with a victory in the 9th round of the national league against Aris (2-1). Now, fans are demanding that they build on this success with their first win in the Champions League.

PSV Team Overview

⚪ This season, PSV are among the leading contenders for the national championship and aim to win the Eredivisie three times in a row for the first time since 2007. After a rocky start in the Champions League, where the "Farmers" fell to Union Saint-Gilloise (1-3) at home, they followed up with a draw against Bayer Leverkusen (1-1) and a sensational victory over Napoli (6-2). Currently, the Dutch side are within the playoff spots, and maintaining their position in this zone is the minimum goal for Peter Bosz's squad.

🔴 In the last Champions League round, the "Farmers" stunned the football world by thrashing the reigning Italian champions Napoli (6-2) on their home turf. Peter Bosz expertly exploited the weaknesses of their opponents and adopted a hybrid system that nullified the "Blues" in transition phases. The remarkable work rate of PSV's flank players led to frequent crosses into Napoli's penalty area. Last Friday, the reigning Dutch champions played another Eredivisie match, this time against Fortuna (5-2), who were unable to offer significant competition to Bosz's men. Ismael Saibari is in outstanding form, contributing to PSV's success with goals and assists in eight consecutive matches across all competitions (10+1).

Latest news

Olympiacos

🎤 Following their 2-1 victory over Aris last weekend, Olympiacos head coach Jose Luis Mendilibar shared his thoughts: "We started the match well and weren't afraid, but we didn't execute our tactical plan as thoroughly as we would have liked. In the second half, we weren't good enough. We need to maintain focus for the full 90 minutes and avoid tense finishes where they shouldn't happen. We have a lot of games, playing every three days. It would be impossible to use the same players, so yes, we regularly rotate to maximize the intensity in our play."

❌ Among the players unavailable for Olympiacos's upcoming European match are Konstantinos Angelakis, Nikos Botis, Remy Cabella, Gustavo Mancha, Alexis Kalogeropoulos, Francisco Ortega, Ruben Vezo, and Yusuf Yazici. Due to suspension, Santiago Hezze will also be absent.

PSV

🎤 Following another successful weekend in the national league, Peter Bosz spoke to the media and shared his thoughts on his team's performance: "In the first half, I think we played quite well. We scored three goals, which is obviously good and important, especially considering the score could have been 1-1. The second half wasn't as entertaining. We added two more goals late on because the game opened up, whereas it was tight in the first half. With our speed and footballing skills, we could have scored even more. We play with a set formation, but within that structure, we frequently switch positions. This positional play is our greatest strength. Every player on the field plays boldly, confidently controls the ball, and knows exactly what's expected of them."

❌ PSV's injury list includes Alassane Pléa (knee injury), Ruben van Bommel (knee injury), and Wessel Koen (knee injury).

🟨 Referee and Yellow Cards

🟨 Referee and Yellow Cards

The referee for this European fixture is the highly-regarded Clement Turpin. Known for his leniency, Turpin allows for a more physical style of play, averaging around 3.22 cautions per match. Notably, in 6 of the last 7 matches involving PSV, there were no more than 4 yellow cards shown. We suggest the following bet – total yellow cards under 4.5.

⚽ Goal Prediction

Both clubs have been involved in high-scoring games this season: Olympiacos with an average of 3.1 goals, PSV with 4.5. Their two head-to-head encounters also saw plenty of goals, averaging 4.5 per game. Moreover, each of the last 5 matches featuring PSV saw at least 3 goals scored. We recommend the following bet – total goals over 2.5.

🚩 Corner Prediction

Let's consider the average number of corners each team has earned this season: Olympiacos – 6, PSV – 6.1. Both clubs will likely adopt an aggressive approach in their upcoming clash, given their standings in the table. It's highly likely that battles on the flanks will be a defining feature of this match. Our editorial choice – total corners over 8.5.

The performance statistics and current trends for both teams indicate a high likelihood of a high-scoring match scenario. José Luis Mendilibar is likely to adopt a more proactive style of play, driven by the home advantage and the pressing need to improve their league standing. PSV, under Peter Bosz, are among the most dynamic teams in Europe. We predict a final score of 2-2, with the key bet being over 2.5 goals.